Low-toxicity metal-organic frameworks: Sustainable solutions for versatile applications
Por:
Obeso, JL, Flores, CV, Gutiérrez, AG, Leyva, C, Valdivia-Corona, JC, Herrera-Zúñiga, LD, de los Reyes, JA, Peralta, RA, Ibarra, IA
Publicada:
1 mar 2025
Ahead of Print:
1 mar 2025
Resumen:
The conventional synthesis of metal-organic framework (MOF) materials generates high amounts of waste solvents, which are directly associated with human and environmental issues. Developing green and affordable MOF materials is necessary since this strategy is based on methods that prioritize sustainability and minimize environmental impact. In this scenario, less toxic metals such as Zn, Zr, Al, and Fe can be applied in addition to linkers from renewable sources. This review discusses eco-friendly synthesis pathways, such as hydrothermal, mechanochemical, at room temperature, ionic liquid, and renewable resources. The current methodologies from specific low-toxicity MOF materials are highlighted. Applications include water treatment, sensing, drug delivery, catalysis, and gas storage, which are mentioned and examined. Interestingly, developing low-impact MOF materials as eco-friendly platforms for diverse applications can be a remarkable opportunity to achieve a sustainable future in the quality of the planet.
Filiaciones:
Obeso, JL:
Inst Politecn Nacl, Lab Nacl Ciencia Tecnol & Gest Integrada Agua LNAg, CICATA U Legaria, Legaria 694 Irrigac, Miguel Hidalgo, Mexico
Univ Nacl Autonoma Mexico, Lab Fisicoquim & React Superficies LaFReS, Inst Invest Mat, Circuito Exterior s-n, Mexico City, Mexico
Tecnol Nacl Mexico, Div Ingn Sistemas Automotr, Tecnol Estudios Super Oriente Estado Mexico, Mexico City, Estado De Mexic, Mexico
Flores, CV:
Inst Politecn Nacl, Lab Nacl Ciencia Tecnol & Gest Integrada Agua LNAg, CICATA U Legaria, Legaria 694 Irrigac, Miguel Hidalgo, Mexico
Univ Nacl Autonoma Mexico, Lab Fisicoquim & React Superficies LaFReS, Inst Invest Mat, Circuito Exterior s-n, Mexico City, Mexico
Gutiérrez, AG:
Inst Politecn Nacl, Lab Nacl Ciencia Tecnol & Gest Integrada Agua LNAg, CICATA U Legaria, Legaria 694 Irrigac, Miguel Hidalgo, Mexico
Leyva, C:
Inst Politecn Nacl, Lab Nacl Ciencia Tecnol & Gest Integrada Agua LNAg, CICATA U Legaria, Legaria 694 Irrigac, Miguel Hidalgo, Mexico
Valdivia-Corona, JC:
Tecnol Nacl Mexico, Div Ingn Sistemas Automotr, Tecnol Estudios Super Oriente Estado Mexico, Mexico City, Estado De Mexic, Mexico
Herrera-Zúñiga, LD:
Univ Autonoma Metropolitana Iztapalapa, Area biofisicoquim, Dept Quim, Mexico City, Mexico
Univ Autonoma Metropolitana, Dept Ciencias Nat, Unidad Cuajimalpa, Mexico City, Mexico
de los Reyes, JA:
Univ Autonoma Metropolitana Iztapalapa, Dept Ingn Proc & Hidraul, Div Ciencias Bas & Ingn, Mexico City 09340, Mexico
Peralta, RA:
Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Div Ciencias Basicas & Ingn, Mexico City, Mexico
Ibarra, IA:
Univ Nacl Autonoma Mexico, Lab Fisicoquim & React Superficies LaFReS, Inst Invest Mat, Circuito Exterior s-n, Mexico City, Mexico
All Open Access; Hybrid Gold Open Access
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