The synthesis and structural characterization of C3 symmetry "star-like" cluster
Por:
Sánchez-Cabrera G., Zuno-Cruz F.J., López-Ruiz H., Rosales-Hoz M.J., Leyva M.A., Rodríguez J.A.
Publicada:
1 ene 2014
Resumen:
The cluster [{Os3(µ-H)(CO)10}3{1,3,5- (µ-SCH2)3C6H3}] has been prepared by the reaction of [Os3(CO)10(NCMe)2] with 1, 3, 5-tris(mercaptomethyl)benzene under mild conditions; the cluster has been fully characterized by IR, NMR spectroscopy, HR-MS, X-ray crystallography and its redox behavior is also described. © 2013 Elsevier B.V. All rights reserved.
Filiaciones:
Centro de Investigaciones Químicas, Universidad Autónoma Del Estado de Hidalgo, Ciudad Universitaria, Carretera Pachuca-Tulancingo km 4.5, Mineral de la Reforma, Hgo CP 42184, Mexico
Departamento de Química, Centro de Investigación y Estudios Avanzados Del I. P. N., Apdo. postal 14-740, 07000 México D. F., Mexico
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