Structural and morphological studies of meso-ethylcarbazole F-BODIPY thin films
Por:
Corona-Sanchez, Ricardo, Arcos-Ramos, Rafael, Maldonado-Dominguez, Mauricio, Amelines-Sarria, Oscar, Jerezano-Dominguez, Alberto, Garcia-Ortega, Hector, Rivera, Margarita, del Pilar Carreon-Castro, Maria, Farfan, Norberto
Publicada:
1 nov 2016
Categoría:
Chemistry (miscellaneous)
Resumen:
In this work, we describe the synthesis of
meso-(9-ethyl-9H-carbazol-3-yl)-4,4-difluoro-4-bora-3a,4a-diaza-s-indace
ne and its incorporation as thin film by vapor deposition on indium tin
oxide. The morphology of the film was analyzed by scanning electron
microscopy and atomic force microscopy showing a granular and
homogeneous structure, contact angle measurements revealed that this
film exhibits a hydrophobic surface. Packing of the compound was
simulated through molecular dynamics and Monte Carlo sampling, and the
electronic features of aggregates were modeled with plane-wave DFT. A
semiconductor behavior for the featured compound in aggregated state,
which compares well with systems applied on electronic devices, is
predicted for the featured F-BODIPY.
Filiaciones:
Univ Nacl Autonoma Mexico, Fac Quim, Dept Quim Organ, Mexico City 04510, DF, Mexico
Univ Nacl Autonoma Mexico, Inst Ciencias Nucleares, Dept Quim Radiaciones & Radioquim, Mexico City 04510, DF, Mexico
Univ Ciencias & Artes Chiapas, Ctr Invest & Desarrollo Tecnol Energias Renovable, Chiapas, Mexico
Univ Nacl Autonoma Mexico, Inst Fis, Dept Mat Condensada, Mexico City 04510, DF, Mexico
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