Energetics and the molecular structure of an ion-paired supramolecular system in water
Por:
Cruz-Vásquez, O., Bernal-Sánchez, L.J., Cervantes, R., Tiburcio, J., Rojas, A.
Publicada:
1 ene 2017
Resumen:
The forces that bind the components of a host-guest complex to generate a stable supramolecular system are noncovalent interactions. The enthalpy of this association, ?asH°, usually measured using calorimetry, quantifies the magnitude of such interactions and is directly related to the stability of the supramolecular complex formed. Using Calvet calorimetry to determine the enthalpies of solution and reaction in water, the enthalpy of association was derived for a supramolecular system formed by the anionic macrocycle anti-disulfodibenzo[24]crown-8 ([DSDB24C8]2-) and the dicationic guest paraquat [PQT]2+. The calorimetric results show an exothermic association process, which indicates the generation of strong interactions between the components of the ion pair. This is consistent with the formation of a stable supramolecular complex [PQT][DSDB24C8], whose spatial arrangement in aqueous solution is proposed based on spectroscopic analysis. © the Owner Societies 2017.
Filiaciones:
Cruz-Vásquez, O.:
Departamento de Química, Centro de Investigación y de Estudios Avanzados Del IPN (Cinvestav), Ciudad de México, Mexico
Bernal-Sánchez, L.J.:
Departamento de Química, Centro de Investigación y de Estudios Avanzados Del IPN (Cinvestav), Ciudad de México, Mexico
Cervantes, R.:
Departamento de Química, Centro de Investigación y de Estudios Avanzados Del IPN (Cinvestav), Ciudad de México, Mexico
Tiburcio, J.:
Departamento de Química, Centro de Investigación y de Estudios Avanzados Del IPN (Cinvestav), Ciudad de México, Mexico
Rojas, A.:
Departamento de Química, Centro de Investigación y de Estudios Avanzados Del IPN (Cinvestav), Ciudad de México, Mexico
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