Human recombinant cementum attachment protein (hrPTPLa/CAP) promotes hydroxyapatite crystal formation in vitro and bone healing in vivo


Por: Montoya G., Arenas J., Romo E., Zeichner-David M., Alvarez M., Narayanan A.S., Velázquez U., Mercado G., Arzate H.

Publicada: 1 dic 2014
Resumen:
Cementum extracellular matrix is similar to other mineralized tissues; however, this unique tissue contains molecules only present in cementum. A cDNA of these molecules, cementum attachment protein (hrPTPLa/CAP) was cloned and expressed in a prokaryotic system. This molecule is an alternative splicing of protein tyrosine phosphatase-like A (PTPLa). In this study, we wanted to determine the structural and functional characteristics of this protein. Our results indicate that hrPTPLa/CAP contains a 43.2% alpha-helix, 8,9%beta-sheet, 2%beta-turn and 45.9% random coil secondary structure. Dynamic light scattering shows that this molecule has a size distribution of 4.8 nm and aggregates as an estimated mass of 137 kDa species. AFM characterization and FE-SEM studies indicate that this protein self-assembles into nanospheres with sizes ranging from 7.0 to 27 nm in diameter. Functional studies demonstrate that hrPTPLa/CAP promotes hydroxyapatite crystal nucleation: EDS analysis revealed that hrPTPLa/CAP-induced crystals had a 1.59 +/- 0.06 Ca/P ratio. Further confirmation with MicroRaman spectrometry and TEM confirm the presence of hydroxyapatite. In vivo studies using critical-size defects in rat cranium showed that hrPTPLa/CAP promoted 73% +/- 2.19% and 87% +/- 1.97% new bone formation at 4 and 8 weeks respectively. Although originally identified in cementum, PTPLa/CAP is very effective at inducing bone repair and healing and therefore this novel molecule has a great potential to be used for mineralized tissue bioengineering and tissue regeneration. (C) 2014 Elsevier Inc. All rights reserved.

Filiaciones:
Montoya G.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Biol Periodontal, Mexico City 04510, DF, Mexico

 Laboratorio de Biología Periodontal, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico

Arenas J.:
 Univ Nacl Autonoma Mexico, Inst Fis, Mexico City 04510, DF, Mexico

 Instituto de Física, Universidad Nacional Autónoma de México, Mexico

Romo E.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Biol Periodontal, Mexico City 04510, DF, Mexico

 Laboratorio de Biología Periodontal, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico

Zeichner-David M.:
 Ostrow School of Dentistry, University of Southern California, United States

Alvarez M.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Bioingn Tejidos, Mexico City 04510, DF, Mexico

 Laboratorio de Bioingeniería de Tejidos, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico

Narayanan A.S.:
 School of Medicine, Department of Pathology, University of Washington, Seattle, United States

Velázquez U.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Biol Periodontal, Mexico City 04510, DF, Mexico

 Laboratorio de Biología Periodontal, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico

Mercado G.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Biol Periodontal, Mexico City 04510, DF, Mexico

 Laboratorio de Biología Periodontal, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico

Arzate H.:
 Univ Nacl Autonoma Mexico, Fac Odontol, Lab Biol Periodontal, Mexico City 04510, DF, Mexico

 Laboratorio de Biología Periodontal, Facultad de Odontología, Universidad Nacional Autónoma de México, Mexico
ISSN: 87563282
Editorial
ELSEVIER SCIENCE INC, 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA, Estados Unidos America
Tipo de documento: Article
Volumen: 69 Número:
Páginas: 154-164
WOS Id: 000344717000020
ID de PubMed: 25263524

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