Is ozone production able to explain the good performance of CabECO® technology in wastewater treatment?
Por:
Rodríguez-Peña M., Barrios Pérez J.A., Llanos J., Saez C., Barrera-Díaz C.E., Rodrigo M.A.
Publicada:
1 ene 2021
Resumen:
This work intends to go a step further in the application of electrochemical technology to produce ozone, by evaluating the production of ozone with a commercial cell registered as CabECO®, which has been previously used to disinfect heavily polluted water in a successful manner, with a view to ascertaining whether this success may be related to the production of ozone. The CabECO® cell is a PEM electrolyzer; that is to say, one in which anode and cathode are connected through a PEM membrane. Since ozone production on the electrolyte is important and depends on the composition of the liquid, attention must be paid to the electrochemical production of scavengers. Dosing of oxygen as microbubbles has a very positive effect on the production of ozone, while temperature regulation is as well considerably important, as the increase in temperature generated by ohmic losses can lead to important decreases in the efficiency of ozone electrogeneration. Rates within the range 0.06–0.60 mg O3 min-1 are observed; this means that the maximum current efficiency reached is as high as 6.11% (considering oxygen as raw matter). These results are extremely promising as compared with other references in the literature, at once they also indicate there is room for further improvements and a long way to prevent the effect of scavengers and increase the efficiency of the process. © 2021
Filiaciones:
Rodríguez-Peña M.:
Department of Chemical Engineering, School of Chemical Sciences and Technologies, University of Castilla La Mancha, Campus Universitario s/n. 13071, Ciudad Real, Spain
Facultad de Química, Universidad Autónoma Del Estado de México, Paseo Colón Intersección Paseo Tollocan S/N, C.P. 50120, Toluca, Estado de México, Mexico
Barrios Pérez J.A.:
Facultad de Química, Universidad Autónoma Del Estado de México, Paseo Colón Intersección Paseo Tollocan S/N, C.P. 50120, Toluca, Estado de México, Mexico
Llanos J.:
Department of Chemical Engineering, School of Chemical Sciences and Technologies, University of Castilla La Mancha, Campus Universitario s/n. 13071, Ciudad Real, Spain
Saez C.:
Department of Chemical Engineering, School of Chemical Sciences and Technologies, University of Castilla La Mancha, Campus Universitario s/n. 13071, Ciudad Real, Spain
Barrera-Díaz C.E.:
Facultad de Química, Universidad Autónoma Del Estado de México, Paseo Colón Intersección Paseo Tollocan S/N, C.P. 50120, Toluca, Estado de México, Mexico
Rodrigo M.A.:
Department of Chemical Engineering, School of Chemical Sciences and Technologies, University of Castilla La Mancha, Campus Universitario s/n. 13071, Ciudad Real, Spain
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