Metodología en línea para la determinación de trazas de los herbicidas 2,4-D y 2,4-DB en agua


Por: Vera-Ávila L.E., Meraz-Lira J.L., Padilla-Cortés P.

Publicada: 1 ene 1997
Resumen:
An analytical method based on Solid Phase Extraction on-line coupled to Liquid Chromatography was developed for the trace determination of the herbicides 2,4-D and 2,4-DB in water. A small precolumn packed with a polymeric reversed phase was used for the extraction of the solutes from the aqueous matrix. Further cleanup of the extract was performed by the transfer of the ionized solutes to a second precolumn packed with an anion exchanger Finally, the latter was coupled to the analytical column for the on-line elution, separation and UV detection of the analytes. The precision (< 3%), recovery (?100%) and detection limits (?, 1 ?g/l) of the method, joined to the possibility of its automation, render it as an ideal mean for the regular monitoring of these two herbicides in natural and treated waters.

Filiaciones:
Vera-Ávila L.E.:
 Depto. de Quimica Analítica, Univ. Nac. Auton. de México, Ciudad Universitaria, Coyoacán 04510 D.F., Mexico

Meraz-Lira J.L.:
 Depto. de Quimica Analítica, Univ. Nac. Auton. de México, Ciudad Universitaria, Coyoacán 04510 D.F., Mexico

Padilla-Cortés P.:
 Depto. de Quimica Analítica, Univ. Nac. Auton. de México, Ciudad Universitaria, Coyoacán 04510 D.F., Mexico
ISSN: 01884999
Editorial
CENTRO CIENCIAS ATMOSFERA UNAM, CIRCUITO EXTERIOR, MEXICO CITY CU 04510, MEXICO, México
Tipo de documento: Article
Volumen: 13 Número: 2
Páginas: 63-71

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