The interaction of poly(methacrylate) radicals with diphenyldiacetylenes
Por:
Canizal G., Burillo G., Muñoz E., Gleason R., Ogawa T.
Publicada:
1 ene 1994
Resumen:
The free radical polymerization of methyl methacrylate (MMA) in the presence of p,p? disubstituted diphenylbutadiynes was studied. Both the rate and degree of polymerization are somewhat lowered by the presence of the diynes, but the propagating radicals were stabilized giving clear ESR signals of the interacted polyMMA radicals at the polymerization temperature of 70°C. The magnitude of the interaction depended on the electron density of the diynes; in the cases of diphenylbutadiyne and dimethoxycarbonyldiphenylbutadiyne, the interaction was more enhanced showing ESR signals with smaller spectra widths and increasing the number of radicals with the polymerization time, while in the cases of electron donor-substituted diynes the interaction was weaker and the radical concentration remained constant during the polymerization. These systems are considered to be examples of the stabilization of transient radicals by the direct interaction of radicals with additives without formation or breaking of chemical bonds. No diacetylenic group was found in the polyMMA obtained. © 1994 John Wiley & Sons, Inc.
Filiaciones:
Canizal G.:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510, Mexico
Burillo G.:
Instituto de Ciencias Nucleares, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México, 04510, Mexico
Muñoz E.:
Instituto de Física, Universidad Nacional Autónoma de México, Ciudad Universitaria, México, Distrito Federal, 04510, Mexico
Gleason R.:
Instituto de Física, Universidad Nacional Autónoma de México, Ciudad Universitaria, México, Distrito Federal, 04510, Mexico
Ogawa T.:
Instituto de Investigaciones En Materiales, Universidad Nacional Autónoma de México, Ciudad Universitaria, México, Distrito Federal, 04510, Mexico
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