Synthesis of calix[4, 5, 6] resorcinarenes using fullerene C60 as template


Por: Klimova T., Klimova E., Vázquez R.A., Gutierrez N.M., Martínez M.

Publicada: 1 ene 2003
Resumen:
We present a new use of fullerene C60 as a template for the synthesis of cyclic resorcinarenes, The cyclocondensation of 2-methyl-resorcinol with benzaldehyde and hexanal in THF, catalyzed by AlCl3, in the presence of 1%, 5%, and 10% fullerene C60, produces calix[4], [5], and [6] resorcinarenes, with the pentamer and hexamer as the major products. The resorcinarenes were characterized by 1H, 13C NMR, FTIR, FAB+ mass spectrometry, and elemental analysis.

Filiaciones:
Klimova T.:
 Univ. Nacional Autonoma de Mexico, Facultad de Quimica, Cd. Universitaria, Coyoacán, Mexico

Klimova E.:
 Univ. Nacional Autonoma de Mexico, Facultad de Quimica, Cd. Universitaria, Coyoacán, Mexico

Vázquez R.A.:
 Univ. Autonoma del Estado de Hidalgo, Instituto de Química, Cd. Univ., Carretera a Tulacingo, Pachuca, Hidalgo, Mexico

Gutierrez N.M.:
 Univ. Nacional Autonoma de Mexico, Facultad de Quimica, Cd. Universitaria, Coyoacán, Mexico

Martínez M.:
 Univ. Autonoma del Estado de Hidalgo, Instituto de Química, Cd. Univ., Carretera a Tulacingo, Pachuca, Hidalgo, Mexico
ISSN: 1536383X
Editorial
Taylor and Francis Inc., 325 CHESTNUT ST, SUITE 800, PHILADELPHIA, PA 19106 USA, Estados Unidos America
Tipo de documento: Article
Volumen: 11 Número: 3
Páginas: 269-281
WOS Id: 000184798000008