Quantitative structural determination of the high coverage phase of the benzoate species on Cu(110)
Por:
Pascal M., Lamont C.L.A., Kittel M., Hoeft J.T., Terborg R., Polcik M., Kang J.H., Toomes R., Woodruff D.P.
Publicada:
1 ene 2001
Resumen:
The local adsorption site and molecular orientation of the benzoate species adsorbed on Cu(110) at 330 K have been determined using O1s scanned-energy mode photoelectron diffraction. The molecule was found to interact with the surface via the carboxylate group, giving a Cu-O bond length of 1.91 Å. The molecules occupy the short bridge sites (the O atoms being slightly displaced from atop sites) and are aligned along the [1?10] azimuth with the molecular plane oriented perpendicular to the surface. © 2001 Elsevier Science B.V. All rights reserved.
Filiaciones:
Pascal M.:
Centre for Applied Catalysis, Department of Chemical and Biological Sciences, University of Huddersfield, Queensgate, Huddersfield, HD1 3DH, United Kingdom
Lamont C.L.A.:
Centre for Applied Catalysis, Department of Chemical and Biological Sciences, University of Huddersfield, Queensgate, Huddersfield, HD1 3DH, United Kingdom
Kittel M.:
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany
Hoeft J.T.:
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany
Terborg R.:
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany
Polcik M.:
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany
Kang J.H.:
Department of Physics, University of Warwick, Coventry CV4 7AL, United Kingdom
Toomes R.:
Department of Physics, University of Warwick, Coventry CV4 7AL, United Kingdom
Woodruff D.P.:
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany
Department of Physics, University of Warwick, Coventry CV4 7AL, United Kingdom
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