ELECTROSYNTHESIS OF IRON AND COBALT MOLECULAR MATERIALS
Por:
Vergara, MES, Rebollo A.O., Bada, JRA
Publicada:
1 ene 2009
Resumen:
Molecular materials are formed by the condensation and rearrangement of molecular units. Their microstructure is of special interest because they are generally formed by a regular molecular pattern that can generate preferential ways for electrical conduction, which is why they are sometimes called quasi-one-dimensional solids or low-dimensional linear chains. This work reports the synthesis and characterization of iron and cobalt molecular materials that were formed through an oxidation-reduction reaction in an electrosynthesis cell from electronic acceptor and donor species. Material characterization was made through infrared (IR) spectroscopy, scanning electron microscopy (SEM) and energy-dispersive spectroscopy (EDS). These materials have a structure of polymeric chains formed from the coordination of the metallic ion to the phthalocyanine with the organic compound 1,8-dihydroxyanthraquinone. The synthesized materials show large chemical and thermal stabilities which may lead to th
Filiaciones:
Rebollo A.O.:
Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico
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