Immobilized Chiral Metal Catalysts for Enantioselective Hydrogenation of Ketones


Por: Somanathan, R, Cortez N.A., Parra-Hake M., Chávez D., Aguirre G.

Publicada: 1 nov 2008
Categoría: Organic Chemistry

Resumen:
Chiral secondary alcohols are useful synthetic building blocks. One direct approach to chiral secondary alcohols is by catalytic reduction of ketones using molecular hydrogen or by asymmetric transfer hydrogenation. This review focuses on recent developments using immobilized chiral metal catalysts, and their role in developing greener chemistry. Immobilization of chiral ligands on silica, polymer, dendrimer and magnetite nanoparticles and their application as catalyst with metals in the hydrogenation of ketones under environmentally friendly solvent conditions is discussed.

Filiaciones:
Cortez N.A.:
 Centro de Graduados e Investigación, Instituto Tecnológico de Tijuana, Apartado Postal 1166, Tijuana, B.C. 22500, Mexico

Parra-Hake M.:
 Centro de Graduados e Investigación, Instituto Tecnológico de Tijuana, Apartado Postal 1166, Tijuana, B.C. 22500, Mexico

Chávez D.:
 Centro de Graduados e Investigación, Instituto Tecnológico de Tijuana, Apartado Postal 1166, Tijuana, B.C. 22500, Mexico

Aguirre G.:
 Centro de Graduados e Investigación, Instituto Tecnológico de Tijuana, Apartado Postal 1166, Tijuana, B.C. 22500, Mexico
ISSN: 1570193X
Editorial
BENTHAM SCIENCE PUBL LTD, EXECUTIVE STE Y26, PO BOX 7917, SAIF ZONE, 1200 BR SHARJAH, U ARAB EMIRATES
Tipo de documento: Article
Volumen: 5 Número: 4
Páginas: 313-322
WOS Id: 000261926900006