Formation of [(L)Ni(µ2-S)x{Fe(CO) 3}x] adducts (x = 1 or 2): Analogues of the active site of [NiFe] hydrogenase
Por:
Stenson P.A., Marin-Becerra A., Wilson C., Blake A.J., McMaster J., Schröder M.
Publicada:
1 ene 2006
Resumen:
The binuclear [Ni(L)Fe(CO)3], 1, and trinuclear [Ni(L){Fe(CO)3}2], 2, complexes adopt unusual structural motifs whereby Fe(CO)3 units bind to [Ni(L)] via ?2-S bridging modes, C=N imine ?-bonds and potential Ni-Fe bonding interactions. © The Royal Society of Chemistry 2006.
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